Friday, December 27, 2019

Eating Disorders And Anorexia Nervosa - 2705 Words

Introduction An eating disorder is characterized as an illness that causes serious interferences to your everyday diet, which includes eating extremely small portions of food or severely overeating (National Institute of Health , 2014). An individual with an eating disorder majority of the time begin eating smaller or larger amounts of food, but the urge to eat less or more can spiral out of control. Severe distress or concerns about weight and body image can also be characterize as an eating disorder (National Institute of Health , 2014). Eating disorders usually appear during teen years or young adulthood, but can also develop during childhood or later in life. Common eating disorders include anorexia nervosa and bulimia nervosa. Eating disorders are real, but however are treatable medical illnesses. Eating disorders coexist with other medical illness such as depression, substance abuse, or anxiety depression (National Institute of Health , 2014). There are other symptoms that are classified as life-threatening if an individual does not receive treatment. Individuals with anorexia nervosa are eighteen times more likely to die at an early age compared with individuals of similar age in the general population. Anorexia Nervosa Anorexia Nervosa is an eating disorder that’s characterized by: ï  ¶ Extreme Thinness (emaciation) ï  ¶ A relentless pursuit of thinness and unwillingness to maintain a normal or healthy weight ï  ¶ Intense fear of gaining weight ï  ¶ Distorted body image, aShow MoreRelatedEating Disorder : Anorexia Nervosa1622 Words   |  7 Pages Bulimia Nervosa To be diagnosed with eating disorder, someone must meet certain criteria. The criterion for diagnosis slightly varies depending on if you are referring to people who (A) fear gaining weight, and have significant weight loss,(B) eating a huge amount of food , then use laxative to remove the binged food, (C) the use of excessive exercise and fasting in order to remove or to reduce the amount of calories consumed, and (D) distorted body image, no matter how thin they become, theyRead MoreEating Disorder : Anorexia Nervosa1658 Words   |  7 Pagesbeen affected by this disorder. The specific disorder that is being referred to in this paper, an eating disorder, is Anorexia Nervosa, the restricting type. An eating disorder â€Å"involve[s] disordered eating behaviors and maladaptive ways of controlling body weight† (Nevid, Rathus, Greene, 2014, p. 335). Another well-known eating disorder is Bulimia Nervosa which is characterized by binging and purging (Nevid, Rathus, Greene, 2014, p. 338). Bulimia is different than anorexia since victims of bulimiaRead MoreEating Disorders And Anorexia Nervosa Essay1948 Words   |  8 Pagesnotion of an â€Å"ideal† body and eating disorders, there is no consensus as to the root cause of eating disorders. The general belief is that eating disorders result from one or more biological, behavioral, and social factors including genetics, unpleasant experiences/trauma, peer pressure, teasing, and family members with eating disorders, among others. There are numerous types of eating disorders. Both women and men are affected by eating disorders each day. Eating disorders can occur from an early ageRead MoreEating Disorders : Anorexia Nervosa1493 Words   |  6 PagesIllness Paper – Anorexia Nervosa February 28, 2016 According to the Mayo Clinic (2016), eating disorders are â€Å"conditions related to persistent eating behaviors that negatively impact your health, your emotions, and your ability to function in important areas of life.† One such eating disorder is anorexia nervosa. Not to be confused with anorexia, which is simply a general loss of appetite that can be attributed to many medical ailments, anorexia nervosa is a serious eating disorder and mental illnessRead MoreEating Disorders: Anorexia Nervosa1653 Words   |  7 PagesAnorexia Nervosa Anorexia Nervosa is one of several subtypes descending from feeding and eating disorders. It is a crippling life-threatening condition marked by a patient placing restriction on energy intake relative to needed energy requirements, resulting in a relentless pursuit of low body weight in the context of age, sex, development and physical health. According to American Psychiatric Publishing of diagnostic and statistical manual of mental disorders (DSM-5) â€Å"Anorexia Nervosa, often timesRead MoreEating Disorders And Anorexia Nervosa947 Words   |  4 PagesEating disorders such as anorexia nervosa, bulimia nervosa, and binge eating disorder consist of emotions, attitudes, and behaviors surrounding weight and food issues. Up to 24 million people of all ages and genders suffer from an eating disorder in the U.S (ANAD, n.d.) bulimia nervosa as well as the other eating disorders are considered to be a female eating disorder, a disorder that only affects women which limits males to seek treatment let alone make aware to other that they suffer from bulimiaRead MoreEating Disorders : Anorexia Nervosa974 Words   |  4 PagesI have always been intrigued with eating disorders, particularly Anorexia Nervosa. When I was 18 years of age, my mother questioned whether or not I was Anorexic and she took me to the family practitioner, who then informed me that I was three pounds shy from being considered underweight. I knew I was thin, but I was really thin, but also really proud of my size. In an African American urban environment being thin was related to illness and drug abuse. I was often teased about how thin and fragileRead MoreEating Disorders : Anorexia Nervosa889 Words   |  4 PagesANAD Eating Disorder Statistics about thirty million people in America of all ages and genders suffer from one of the three main eating disorders. Many people suffer from more than one of the eating disorders. Only 1 in 10 individuals receive the treatment that is needed to recover(AND A). Often eating disorders are known to be triggered by outside factors in their life, but studies show that it is more likely to be a part of their genetics. According to Webster the definition of an â€Å"Eating Disorder†Read MoreAnorexia Nervosa- Eating Disorder1685 Words   |  7 PagesEffects of anorexia are mostly seen on the outside of the victim’s body, but do not be fooled. This detrimental eating disorder affects one’s mind just as much as it would the body. What Anorexia does to the mind is that it distorts the way one views their body. Victims of anorexia become fixated on their body image and overly critical about their flaws and weight. Even being obviously underweight, Anorexics will continuously deny that they have a problem and continue with their fatal practices.Read MoreEating Disorders : Anorexia Nervosa1462 Words   |  6 Pagessuffer from many illnesses, one in particular is eating disorders. There are many types of eating disorders, but there are three common ones that are known today, which are anorexia nervosa, bulimia nervosa, and binge-eating disorder. Eating disorders are not healthy, thi s type of disease can be very fatal and crucial to one s health   mentally, physically, and socially. The purpose of this report is to provide background information about eating disorders, strategies to prevent this illness from occurring

Thursday, December 19, 2019

Essay about 9/11 by Robert Pinsky - 1105 Words

Without falling into jingoism or being over-sentimental, Robert Pinskys poem 9/11 generates a commendable ode to the spirit that drives this country, in addition to revealing the American culture for what it truly is Ââ€" enthusiastic and frivolous, courageous and fallible, petty and resilient. For most Americans, September 10th is Before, and everything since is After. Citizens from every state across the U.S. responded immediately to the attacks by giving blood and donating much-needed items to shelters, where an overwhelming amount of aid was sent to assist the itinerant victims. However, its ironic that the American people Ââ€" who were so benevolent and charitable for the populace of the 9/11 tragedy Ââ€" would turn their backs on and†¦show more content†¦Americas togetherness, our connectivity with each other, proved false after beginning to fall apart as more and more time passed, and the culture moved away from horrific and terrifying to thats so sad and Im so sorry. When Pinksy mentions notorious historic figures, he is proposing that Americans are not as together as we would like to seem: Will Rogers was a Cherokee, a survivor Of expropriation. A roper, a card. For some, A hero. He had turned sixteen the year That Frederick Douglass died. Douglass was twelve When Emily Dickinson was born. Is even Donald Half-forgotten?Ââ€"Who are the Americans, not A people by blood or religion? (Lines 21-27) By including familiar faces such as Frederick Douglass and Emily Dickenson co-habitating along side a half-forgotten Donald Duck, he is idolizing real Americans, actual people who contributed to freedom and the ideals on which our founding fathers hoped our nation would achieve. I believe this is why Pinksy includes these names in the poem Ââ€" for the very fact that they were ordinary people who achieved many great things Ââ€" instead of including mainstream celebrities such as Thomas Jefferson and George Washington. Somehow previous generations are dismissed and forgotten when people are not personally affected or connected to the past. A source of AmericasShow MoreRelatedLiterature Review - Representation of Women in Walt Disney Cartoon Characters.3370 Words   |  14 Pagesidea of motherhood not being important in Disney? Most of the characters mothers are deceased or not mentioned- with the father figure being the be all and end all of decisions. 9) Why Disney has changed certain things from the original fairytales? 10) Is there any change in the characterization of the cartoons ? 11) What about the Villains in Disney- Why all evil women have special powers in their aid whereas males simply use violence? Is Disney sexist? 12) Also why are most of the princesRead More Effects of Television on Our Society Essays6952 Words   |  28 PagesChristianity in the show). â€Å"We try to represent people’s honest attitudes about religion,† producer Scully says. So, in multiple shows, they paint a hilarious yet bare truth about how this religion is seen and treated by our society in everyday life. Mark Pinsky, author of The Gospel According to the Simpsons, and longtime journalist for the Orlando Sentinel, says that he finds â€Å"God, faith and spirituality abundant in The Simpsons. Christians and Christianity are more a part of The Simpsons than of any otherRead MoreAnalysis Of One Flew Over The Cuckoo s Nest 3755 Words   |  16 Pagesfanatics like Jed Parry, who are left to voice their delusions and chisel away at the rational modern society we have now supposedly become, should be stopped. Writing in the 1990s, a decade which would be the precursor to the terrorist attacks of 9/11 an d 7/7, McEwan was fully aware of the dangers of ‘conservative extremism’ at a time where the West had to grapple with the new threats facing their nations. Hence, Joe’s struggle to maintain his scientific ‘’thought process’’ in the face of Jed’sRead MoreContemporary Issues in Management Accounting211377 Words   |  846 PagesData available Typeset by SPI Publisher Services, Pondicherry, India Printed in Great Britain on acid-free paper by Antony Rowe Ltd., Chippenham, Wiltshire ISBN 0–19–928335–4 978–0–19–928335–4 ISBN 0–19–928336–2 (Pbk.) 978–0–19–928336–1 (Pbk.) 1 3 5 7 9 10 8 6 4 2 3 FOREWORD ‘ Michael Bromwich is an exemplar of all that is good about the British tradition of academic accounting. Serious in intent, he has striven both to illuminate practice and to provide ways of improving it. Although alwaysRead MoreContemporary American Poetry and Its Public Worlds Essay8159 Words   |  33 Pagesdeveloped what I have called a poetics of contingency; at the other a poetics of wisdom attempting to realize traditional ideals in new ways. The poetics of contingency emerges in several different forms during the 1950s--especially in the work of Robert Creeley, Frank O Hara, and Sylvia Plath, the poets who most definitively put to rest the New Critical well-made lyric demonstrating sensitive and capacious meditative judgment. Each of these poets explored ways of resisting the artificiality of lyric

Wednesday, December 11, 2019

Contract Law Deceptive Business Conduct

Question: Discuss about the Contract Law for Deceptive Business Conduct. Answer: Issue of the Case: Whether the University is legally obliged to pay the extra cost for work while it is already mentioned in contract that the work must be completed by 1st March, 2016. Facts of the Case: In Western Australia, a regional University made a contract with Marina Construction Limited (MCU) for some renovations in an old hotel to convert it into a hostel so that it can be used for students to be enrolled for the first semester. According to the contract, the work must be completed by 1st March 2016 but later on, MCU have discovered that the structure of the building require a lot of reparation and it is impossible for them to complete the work within given time-period. The directors of MCU recommended the representatives of the University that if the price of the contract is increased to a certain amount, they would be able to hire extra labors to complete the contract within given time. The University agrees to the terms and work continues to complete it by 1st March. The University council is upset with the additional payment and wants an advice whether the University is legally obliged to pay the extra cost for the work. Rules: Australian Contract Law: The Contract law which is framed in Australia comes from the English Common law and does not follow any codified or statute law[1]. The courts of Australia give considerable significance to the intentions of the parties making contract which are kept as evidences in document or written form. According to this law, a contract is considered as a promise between the parties involved in a contract which can be legally enforced and is an undertaking by them to perform or to refrain from doing something. It requires an agreement between the parties, their consideration, their agreement for any legal formalities, and legal capacity to contract. Consumer law framed in Australia states that an individual is considered to be involved in ambiguous or unreliable conduct in trade or commerce, if he/she misleads or deceive or likely to mislead or deceive the other party involved in the contract[2]. Contract law does not provide a party with a right to get away from the contractual obligations if a party is being mistaken about some aspects or clauses of the contract. In unilateral type of mistake, one party is mistaken about some aspect of the contract but the other is not. However, in common law, there is no provision of remedy for unilateral mistake but law of equity plays a significant role in such circumstances. Contracts are considered to be discharged by way of performance of the contractual responsibilities by the parties. According to general rule of contractual responsibilities, a contract must be performed completely and exactly according to the mentioned clauses in the contract. It means that contract must be discharged fully and exactly according to the terms and conditions of the contract. Application: Considering Contract law of Australia, in this case, MCU should be held guilty to deceive the University as it was clearly mentioned in the contract that the work will be completed within the given time and a certain fixed amount of money was decided for the completion of the work. However, after starting construction work, being not capable to complete the work within time, they demanded extra money. It is simply a violation of contract. Considering the case of Smith v. Hughes[3], in which the decision given by the Court was that the plaintiff must have known of the defendant's mistake at the time of making of the contract[4]; it is considered as the duty of MCU to calculate the amount of time required to complete the construction work but unaware of this, they got involved in the contract. Hence, they should be held liable under the law for demanding extra amount for completing the task within time. Taking into consideration unilateral type of mistake under Contract law, contractual remedy should be provided to the University due to unilateral type of mistake done by MCU. The act done by the corporation is not according to the general rule of contractual responsibilities. MCU has demanded extra price by the University to complete the work on time which is mentioned in the contract. The contract is not being discharged exactly according to the terms and conditions agreed by both the parties. Thus, MCU should be held liable to violate the general rule of contract also. Conclusion: After discussing the law of Australia for the purpose of Contract, it is evident that MCU is guilty of violation of contract made with the University. The corporation should be held liable under the Contract Law of Australia and should compensate the University accordingly[5]. Remedies: In case of violation of contract by one party, the non-violating party must be entitled to damages suffered by them as a matter of right. Damages are considered as an alternative for performance and put the non-violating or suffering party in the position it would have been if the contract had been performed according to the terms and conditions mentioned in the contract. Thus, MCU should be held liable to pay the extra amount taken by it in order to perform the contract on time. Common law also provides equitable remedies to the suffering party but it is awarded at the judgment of the court. However, the court is not obliged to award the remedies even when the contractual violation is established. Therefore, the University should file case in the court against MCU for violation of contract and demand compensation from the corporation. However, according to the procedure of Contract law, university will be compensated only for the extra amount of money paid for the performance of the contract if the corporation will be completing the given task within time. If it fails to perform the contractual obligations within time, the amount of compensation shall be increased according to the circumstances. Works Cited Australian Contract Law, 2013. Misleading or Deceptive Conduct. [Online] Available at: https://www.australiancontractlaw.com/law/avoidance-misleading.html [Accessed 22 August 2016]. Johnson, M. Millar, J., 2014. Doing Business in Australia: Contract law. [Online] Available at: https://www.claytonutz.com/knowledge/2014/june/doing-business-in-australia-contract-law [Accessed 22 August 2016]. Legal Services Commission, 2004. Right to recover damages. [Online] Available at: https://www.lawhandbook.sa.gov.au/ch10s02s11s02.php [Accessed 22 August 2016]. TAYLOR V. JOHNSON: UNILATERAL MISTAKE IN AUSTRALIAN CONTRACT LAW (1985). [1] Johnson, M. Millar, J., 2014. Doing Business in Australia: Contract law. [Online] Available at: https://www.claytonutz.com/knowledge/2014/june/doing-business-in-australia-contract-law [Accessed 22 August 2016]. [2] Australian Contract Law, 2013. Misleading or Deceptive Conduct. [Online] Available at: https://www.australiancontractlaw.com/law/avoidance-misleading.html [Accessed 22 August 2016]. [3] (1871) L.R. 6 Q.B. 597 [4] TAYLOR V. JOHNSON: UNILATERAL MISTAKE IN AUSTRALIAN CONTRACT LAW (1985) [5] Legal Services Commission, 2004. Right to recover damages. [Online] Available at: https://www.lawhandbook.sa.gov.au/ch10s02s11s02.php [Accessed 22 August 2016].

Tuesday, December 3, 2019

The Canterbury Tales Essay Example For Students

The Canterbury Tales Essay In the poem, The Canterbury Tales, there were two characters that were completely from each other. The two characters were two parts of a whole which is a dichotomy, for example there were a ying and a yang. The parson was the light side, which is the ying and the friar represents the yang. The parson is a good man who is poor, but he is rich in holy thoughts and works. He was satisfied with himself for knowing he had very little, and he was also very benign, and was also ready to give his poor parishioners anything that he could get. Chaucer does this to show the good side of The Church, and Chaucer does not do that real often in his tales. We will write a custom essay on The Canterbury Tales specifically for you for only $16.38 $13.9/page Order now The friar is the exact opposite. He was the best friar around because no one knew as much dalliance and sweet talk as he did. He knew all the taverns, innkeepers and barmaids more than the lepers and beggars. He believed that being seen with paupers was not good for a man in his position and there was no profit to be made with them, unlike with the rich and the sellers of food which is profitable. He was also the best beggar in the area and no one else moved into his turf. In his tale he was a man that said he would pretend that he was holy. He also gives the best pardons to the people that give him the maximum amount of money. In the poem, Chaucer makes a statement that says he is the only person that practices his profession accurately. During the Middle Ages friars were supposed to attack sinners and evil away from the people, but they soon figured out that this was a profitable business. The most ironic thing about the friars was that they were supposed to drive evil away from people, but they committed evil deeds themselves. In Chaucers mind the parishioner was the stereotype example of what priesthood should be like. If someone could not pay there taxes to the church he did not believe in excommunicating them, unlike a lot of other people during this time. The parson is a prime example of a Shepard tending to his flock of sheep. He always protects them from evil doers and sinners, like they were wolves trying to eat them.

Wednesday, November 27, 2019

Simplest alkylphenols isomeric mixtures Essay Example

Simplest alkylphenols isomeric mixtures Essay Introduction Cresols Cresols merely are isomeric mixtures of the simplest alkylphenols. Its molecular expression is C7H8O, and it occurs in three chief isomers: A corporate term used for the mixture of the three isomer is tricresol. As pure substances, o- and p- methyl phenol are crystalline ; m-cresol is a syrupy oil at room temperature. { 2 } Cresols are colorless and have a phenol-like smell. They are extremely flammable, reasonably soluble in H2O and soluble in ethyl alcohol, ether, propanone, or alkali hydrated oxides. Cresols and cresol derived functions ( quintessences and esters ) are by and large distributed in nature. They are formed as metabolites of assorted micro-organisms and are found in the piss of mammals. Humans eliminate, on norm, 87 milligram of p-cresol per twenty-four hours in the urine [ 3 ] . Assorted signifiers of methyl phenols can besides be detected in the infusions and H2O vapour distillations of some workss. Minute sum of methyl phenols can besides be found in certain nutrient and drinks e.g tomatoes, mushrooms and black tea We will write a custom essay sample on Simplest alkylphenols isomeric mixtures specifically for you for only $16.38 $13.9/page Order now We will write a custom essay sample on Simplest alkylphenols isomeric mixtures specifically for you FOR ONLY $16.38 $13.9/page Hire Writer We will write a custom essay sample on Simplest alkylphenols isomeric mixtures specifically for you FOR ONLY $16.38 $13.9/page Hire Writer Considerable sums of methyl phenol may be formed and enter surface Waterss if woods are pyrolyzed by pyroclastic flow from break outing vents, as happened after the eruption of Mount St. Helens in 1980 [ 3 ] . Coal pitch was originally the exclusive beginning of methyl phenol production until universe war 2, after which they were besides obtained exhausted refinery caustics. Since the mid-1960s, they have been produced synthetically on an progressively big graduated table. Approximately 60 % of the planetary production of methyl phenol is now met by man-made paths Properties: Chemical Properties: Sourness Cresols are weak acids and that dissolve in aqueous base to organize H2O stable salts known as cresolates. They can hence be extracted into Na hydroxide solution from dissolver that are non mixable with H2O. There sourness is so low ( pKa 10.1 10.3 ) to the extent that it can be liberated from cresolates by H sulphide and C dioxide. Chemical reactions Cresols can undergo etherification with alkyl halides, dialkyl sulphates, dialkyl carbonates and toluenesulfonic acid esters. They besides undergo esterification with acyl anhydrides or acyl chlorides to organize the corresponding tolyl esters. Chemical reaction with sulfur oxytetrafluoride at 150 C will give flourotoluene, whilst reactions with diphenylphosphine trichloride at 220 C and phosphorus tribromide at 280 C will give chlorotoluene and bromotoluene severally Hydrogenation can happen in vapour stage at 300-400 C and at force per unit area of up to 8MPa in the presence of accelerators that contains passage metals and aluminium oxides to give methylbenzene. Oxidation reactions of methyl phenols depend on the oxidizing agent, reaction conditions and the place of the methyl group. This reaction occurs by free extremist mechanisms and the green goods assorted compounds such as hydroquinones, quinols, quinines, furans and tolyl quintessences Cresols readily undergo electrophilic permutation. The substituent enters the karyon chiefly in the o- and p- places relative to the hydroxyl group. If o- or p methyl phenols is heated with friedel-crafts catatlyst, isomeriztion to m-cresol, which is thermodynamically the most stable, occurs. When heated with CO2 under force per unit area dry base metal cresolates produces hydroxyl ( methyl ) benzoic acid. When methanal is added to cresols in the presence of base and at room temperature hydroxyl ( methyl ) benzyl intoxicants are form, but in the presence of an acid and at higher temperature the intoxicant condenses to organize high molecular rosins. At high temperature unalloyed steel is attacked by methyl phenols to a noticeable extent, the badness of the onslaught depends on the H2O content. Chromium steels are somewhat more immune to assail by methyl phenols than unalloyed steel. Tantalum is considered to be wholly immune to cresols. The caustic behaviour of methyl phenols can alter significantly with the presence of other compounds. The physical belongingss of methyl phenols shown in the tabular array below: Separation of methyl phenols O-cresols can easy be separated from the mixture of the three isomers through distillment. This is non the instance for m-cresol and p-cresol due to the minute difference in their boiling points. Below is the list of some the procedures employed in the separation of m-/p- methyl phenol mixtures: Crystallization: Although m and P methyl phenols have near boiling points, there is an appreciable difference in there runing point which indicates that crystallisation can be used in for separation. Adsorption: Alkali metal-modified or alkalic earth metal-modified zeolites, and besides Ti dioxide, adsorb p-cresol more strongly than m-cresol { 4 } . Therefore a mixture of P and m methyl phenols can be separated in an surface assimilation column and dissolved once more with a suited desorbing liquid such as an aliphatic intoxicant, e.g. , a mixture of 1-hexanol and 2-heptanol, or a ketone Separation via Ester or salt formation: The female parent spirits enriched with p-cresol ( e.g. , to a m/p ratio of 35: 65 ) from the precipitation with sodium ethanoate can respond with oxalic acid to give the semiester or diester, which is precipitated on chilling to 20 A °C. The ester is separated and so hydrolyzed by heating with H2O at 85 % in the presence of the several nonionic dissolver. The oxalic acid may be precipitated on chilling and recycled. The p-cresol dissolves in the organic dissolver, from which it is isolated by distillment. The jumping usage of both procedures separates m- and p-cresol about wholly { 4 } Alkylation with Isobutylene: Alkylation of m-/p- cresol mixture gives a mixture of butylated m-cresol and p-cresols. Dealkylation of either or both of these merchandises makes it possible to acquire pure m-cresol and p-cresol. Uses O-cresol O-cresol can be chlorinated to 4-chloro-o-cresol and can be used as a get downing stuff for the production of chlorophenoxyalkanoic acids, 4-chloro-2-methylphenoxyacetic acid and 2- ( 4-chloro-2-methylphenoxy ) -propionic acid ; these acids are of import as selective weedkillers. A smaller proportion of o-cresol can besides be nitrated to 4,6-dinitro-o-cresol, which can be used in the production and distillment of cinnamene as a polymerisation inhibitor. O-cresol of high pureness is now being processed to epoxy-o-cresol novolak rosins which are utile as sealing stuffs for incorporate circuits ( french friess ) . Normal choice o-cresol is besides employed in the alteration of traditional phenol-formaldehyde rosins. O-cresol is besides of import as a precursor of assorted dye intermediates, of which the most of import in footings of measure is o-cresotinic acid ( o-hydroxymethylbenzoic acid ) produced by the kolbes synthesis. { 5 } This acid can besides be used in the pharmaceutical industry. O-cresols can be used as a dissolver, straight or after it has been hydrogenated to 2-methylcyclohexanol or 2-methylcyclohexanone. O-cresol in the signifier of its carbonated ester is used as a get downing stuff in the synthesis of coumarin. Alkylation of o-cresol with propene green goodss carvacrol, which is used in aromas and as an antiseptic. Alkylated with isobutene, little sums of o-cresols can be used as get downing stuffs in the production of antioxidants and in the production of constituents used for thermic recording stuffs. M- and p- methyl phenols A mixture of these two isomers can organize a starting stuff for contact insect powders like O, O-dimethyl-O- ( 3-methyl-4-nitrophenyl ) thionophosphoric acid and O, O-dimethyl-O- ( 3-methyl-4-methylthiopheny ) thionophosphoric acid. Although pure m-cresol can besides function this intent. M-cresol is used in the synthesis of phenyl m-tolyl quintessence ( m-phenoxytoluene ) , which can so be oxidized to m-phenoxybenzaldehyde, which can served as a edifice block in the production of insect powders of the pyrethroid type. An of import get downing stuff for the synthesis of vitamin E is 2,3,6-trimethyphenol, this can be produced by the selective methylation of pure m-cresol with methyl alcohol. Alkylation of m-cresol with isobutene green goodss 6-tert-butyl-m-cresol which can be condensed with sulfur bichloride to give 4,4A?-thiobis ( 6-tert-butyl-m-cresol ) , an of import antioxidant for polythene and polypropene. More antioxidants are produced from 6-tert-butyl-m-cresol by condensation with butyraldehyde or crotonaldehyde. In Japan, amination of m-cresol is used to bring forth m-toludine 4-chloro-m-cresol which is used as a germicide and preservative can be produced by selective chorination of either pure m-cresol or a mixture of m-/p-cresols. An of import field of application for proficient methyl phenol mixtures is the production of modified phenoplast rosins by condensation with methanal. The suitableness and monetary value of methyl phenol mixtures for this purpose depends on their content of m-cresol, the most reactive of the three isomers. Cresol mixtures are extremely of import as dissolvers for man-made rosin coatings ( wire enamels ) . { 5 } Impersonal phosphorous acid esters which are used as fire immune hydraulic fluids, additives in lubricators, air filter oils and flameproof plasticisers for PVC and other plastics can be produced from mixtures of m-/p-cresols that do non incorporate the o isomer. Due to its bactericidal and fungicidal belongingss, methyl phenols can be used as germicides in soap. Condensation of methanal with cresolsulfonic acid and Sulfonation of novaks obtained from methyl phenols are used to bring forth man-made tanning agent. Cresols are besides used as wood preservatives. Cresols are used in Ore floatation, fiber intervention, as metal degreaser, as pull outing dissolvers, and as agents for taking carbonisation sedimentations from internal burning engines. Hydrogenation of methyl phenols green goodss methylcyclohexanol and methylcyclohexanone which are used in the pigment and fabric industries. Xylenols Xylenol or dimethylphenol is an arene compound with two methyl groups and a hydroxyl group. The name xylenol comes from xylol and phenol Xylenol occurs in six isomeric signifiers: Commercially, 2-6 xylenol is considered to be the most utile out of the six isomers. Properties The Physical belongingss are shown in the affiliated tabular array: Xylenols are colourless crystallising compounds that are soluble in intoxicant, propanone, and in many other organic dissolvers. They are less soluble in H2O than the methyl phenols { 5 } . There sourness is by and large lower than that of methyl phenol, except for 3,5-xylenol. They are normally soluble in aqueous Na hydrated oxide but the extent of solubility depends on the isomer. The chemical belongingss are similar to that of the methyl phenols Separation: Crude xylenols can be separated into its different isomers by fractional distillment. The different isomers at the matching boiling point are highlighted below. 2,4-xylenol and 2,5-xylenol are contained in the fraction boiling point at 208-212 A °C at 101.3 kPa. Crystallization method is used to divide these isomers since the difference in their boiling point at 101.3 kPa is 0.2 C 2,3-Xylenol is isolated from a fraction boiling at 215-218 A °C by selective dephenolation with dilute aqueous Na hydrated oxide, debut of the free phenols into milk of calcium hydroxide, and depriving with steam ; it can so be purified by recrystallization from benzine { 5 } 3,5-xylenols is crystallized by chilling the fractions with boiling points scope of 218-221 C, 3,4-xylenols is besides obtained this manner but with a fraction of boiling points of 223-225 C Separation of 2,6 xylenols: In the azeotropic distillment of the m-/p-cresol fraction with steam, 2,6-xylenol crystallizes from the condensate. 2,6-Xylenol can be distilled from cresolate caustics because of its lower sourness, after which it is obtained from the condensate by extraction with benzene.. In fractions rich with 2,6-xylenol like the one obtained from synthesis by the methylation of phenol, the 2,6-xylenol can be separated from m- and p-cresol and other phenols by countercurrent extraction with aqueous Na hydroxide-hydrocarbon mixtures. Uses Xylenol mixtures can be used as dissolver for wire enamels, germicides, fabric aides and in ore floatation. Xylenol-formaldehyde rosins can be manufactured from mixtures rich in 3,5-xylenols and xylenols with two H atoms in the o- and p-positions Nontoxic plasticiziers and trixylenyl phosphates which are used as fire-retardant hydraulic fluids can be produced from Xylenols that are without an o-methyl group. 2,4-/2,5-Xylenol mixtures constitute natural stuffs for antioxidants, particularly those intended for gasolene ( e.g. , 6-tert-butyl-2,4-dimethylphenol ) and rubber [ e.g. , 2-methyl-1,1-bis ( 2-hydroxy-3,5-dimethylphenyl ) propane ] . { 5 } Pure 2,5-xylenol is besides used in the pharmaceutical industry for the production of lipid reducing agents. 2,6-xylenols is primary used to bring forth poly ( phenylene oxide ) resins. Oxidation of 2,6-xylenol gives 2,6-xylenol dimer, a forte monomer to bring forth epoxy rosins for encapsulating advanced semiconducting materials. { 6 } Condensation of 2,6-xylenol with acetone green goodss 2,2-Bis ( 4-hydroxy-3,5-dimethylphenyl ) propane ( tetramethylbisphenol A ) which is used as an intermediate for polycarbonates whose belongingss are similar to that of poly ( phenylene oxide ) resins. Treated with ammonium hydroxide, 2,6-Xylenol outputs 2,6-dimethylaniline, which is used in the industry of pesticides and besides in the production of pharmaceuticals. Xylenols are besides used in little sums in the synthesis of dyes and in the production of aromas. Feedstock: There are several paths to bring forth methyl phenols and xylenols runing form natural paths to man-made paths, some of which are listed below: Sythentic paths from methylbenzene Splitting of cymene hydroperoxide Methylation of phenol Production from coal pitch Production from naptha checking The feedstock required mostly depends on the production path and the specific isomers required. The procedure paths are extensively covered in subdivision 4 Safety Cresols and xylenols burn the tegument and mucose membranes through debasement of proteins, likewise to phenols. Initially white and later chocolate-brown black necroses appear on the tegument. { 5 } Certain persons may demo hypersensitivity symptoms in add-on to the caustic consequence. Absorption occurs even more quickly when the compounds are in the liquid province. Severe harm to the wellness can happen even if the open portion of the tegument is comparatively little. Inhalation of the compounds besides leads to severe poisoning whose symptoms includes concern, giddiness, sickness, purging, muscular vellication and depending on the badness, loss of consciousness. As these compounds are quickly absorbed through the tegument, a causal intervention of the toxic condition is non yet in being, although a good first assistance step would be to rinse it off the tegument every bit shortly as possible. A mixture of polythene ethanediol and ethyl alcohol in the ratio of 2:1 has been proven to be the most suited for this intent and it is extremely recommended that it is readily available in countries where methyl phenols and xylenols are being handled. It is besides recommended that when working with these two compounds, it should be done in closed setup if possible. Suites should be good ventilated and safeguards such as air locks and gas compensation technique should be in topographic point to avoid the inspiration of cresol/xylenol vapor. With brassy point of the different isomers of both compounds runing from 80-87 C, the storage and transit are handled with extreme attention. Cresols and xylenols are normally stored in well-sealed containers in a cool and good ventilated country. During transit, well-sealed and protective containers are besides used ; the high flammability and the caustic nature of the substances are besides indicated on the label. Further information sing the safety and handling of methyl phenols and xylenols can be found in the MSDS included in the appendices and subdivision 4 Environmental Consideration Cresols and xylenols are readily biodegradable, although cresol degrades faster than xylenol. Waste H2O incorporating 900mg/l of methyl phenols can be treated utilizing biological works with appropriately adapted bacteriums. In the environment, methyl phenols are degraded at low concentrations, particularly by bacteriums that are widely distributed in the dirt and H2O ( peculiarly Pseudomonas species ) . Degradation by other beings, including barms, Fungis, algae, and higher workss, every bit good as by photolysis, is besides known. { 6 } Because of these grounds methyl phenols and xylenol do non prevail in the environment. Due to its toxicity in H2O, there are rigorous Torahs regulating their release into the aquatic environment. Liquid methyl phenols and xylenols can be absorbed with absorbents like sawdust, peat or diatomaceous earth and so later fire off in particular incineration workss. â€Å"Solidified merchandises should non be dissolved, but removed automatically. Concluding residues can be neutralized with 2 3 % aqueous Na hydrated oxide and flushed with plentifulness of H2O into suited drains taking to a biological effluent intervention plant† Cresols and xylenols nowadays in waste gas watercourses can be removed by scouring the watercourse with sodium hydrated oxide or by firing. Adsorption on activated C is another method that can be used ; this method can roll up up to 0.5kg of cresols/kg. The adsorbate is recovered when the activated C is regenerated. Market and Resources Size The entire production of methyl phenol was estimated to be 175,000 t/a, of which 105 000t was produced via man-made path and 70 000t via natural paths. Approximately 42,000t are produced in the United States, 50,000t in Europe, 58000t in Japan and 25000 T in South Africa. The natural methyl phenol comes from the gasification of coal, from coaking of coal and exhausted refinery caustics in a ratio of 50:35:15. { 7 } The entire end product of methyl phenols have been worsening in the past decennary, this fact can be attributed to a figure of grounds which includes worsening markets, the entryway of 2,6-xylenol manufacturers into the o-cresol market, the outgrowth of South Africa in the market for purified methyl phenols, the worsening handiness of coal pitchs from coking procedures and of exhausted refinery caustics, and the increasing environmental costs. Approximately 165,000t of xylenols are produced yearly, chiefly from United States, Western Europe, and Japan. Xylenol mixtures histories for 30 000 40 000 T, 2,6-xylenol for 125 000 T, and the staying single isomers ( particularly 2,4- , 2,5- and 3,5-xylenol ) , obtained by synthesis or isolated from mixtures, for 10 000 T. Xylenol mixtures are chiefly obtained from exhausted refinery caustics and coal pitchs in the United States, South Africa and Europe As mentioned earlier, there are several procedure paths to methyl phenols and xylenol, nevertheless the most utilised 1s are: Production from coal pitch Production from naptha checking Methylation of phenol Synthesis paths from methylbenzene. The inside informations for each of the named procedure paths will be covered in the ulterior facet of this study, below is merely an lineation of the procedure paths and states where it is being utilized. Production FROM COAL TAR Historically, Cresylic acids ; a corporate name for the mixture of methyl phenols phenol and xylenol have been produced from coal pitch isolated during the gasification or carbonisation of coal. The chief feedstock for this procedure is coal pitch and the merchandise is normally a mixture of methyl phenol, phenol and xylenols. Countries and makers that employ the usage of coal pitch in the production of Cresylic acid are outline as follows: Cresylic acids have been traditionally produced from low-temperature coal pitchs in the United Kingdom, with the most outstanding manufacturer being Coalite chemicals. Cresylic acids and 3,5-xylenols are produced in Germany by RuA? tgers VFT AG utilizing coal pitch chemical science â€Å"CdF Chimie in France and Nippon Steel Chemical Co. of Japan have besides been bring forthing some coal pitch based cresols† { 1 } SASOL of South Africa is a major manufacturer of Cresylic acid, and it has been reported methyl phenols of 99 % pureness can be supplied for selected clients. Production FROM NAPTHA CRACKING In the USA, methyl phenols and xylenols have been produced from the naphtha fractions from catalytic thermic snap. The merchandises normally contain up to 1 % C6-C8 phenols. Sulphur Compounds such as alkyl and aryl thiols are treated with concentrated alkalic solutions in a procedure known as sweetener and methyl phenols and xylenols are recovered from exhausted acerb washes, bring forthing Na cresolates/xylenolates. The composing of the exhausted acerb cresolates scopes from 20-25 % of C6-C8 phenols and 10-15 % sulfur compounds. The acerb washes are so collected by companies that produce methyl phenols of which Merichem of Houston, Texas is the most outstanding. This method is largely confine to the USA because of the deficiency of cresolates feedstocks in other states. METHYLATION OF PHENOL This procedure is mostly used for the production of o-cresols and 2,6 xylenols, the procedure consists of merely one reaction measure based on phenol, which is comparatively expensive. Separating the merchandises can besides be dearly-won because of the similarity in boiling points. This procedure can either be carried out in the vapor stage or the liquid stage, with the most common path being the vapour stage path. Methylation in the vapour stage is utilized by: General Electric Co. in the United States ( capacity 5000 t/a of o-cresol and 70 000 t/a of 2,6-xylenol ) Inspec Fine Chemicals ( once Man-made Chemicals, now a portion of Laporte ) in the United Kingdom ( capacity 10 000 t/a of o-cresol and 2,6-xylenol, but the works is besides used for the production of 2,4-xylenol by methylation of p-cresol and for 2,5-xylenol and 2,3,6-trimethyphenol by methylation of m-cresol ) Chemopetrol in the Czech Republic ( capacity 10 000 t/a of o-cresol, m/p-cresol, 2,6-xylenol and other xylenols ) Nippon Crenol ( joint venture of Asahi Chemical Industry and Nippon Steel Chemical Company ; capacity 8000 t/a of o-cresol and 15 000 of t/a 2,6-xylenol ) , GEM Polymers ( joint venture of General Electric Company, Mitsui Chemicals Co. , and Mitsui Toatsu Chemicals ; ( capacity 2500 t/a of o-cresol and 11 500 t/a of 2,6-xylenol ) , Mitsubishi Gas Chemical Company ( capacity 5000 t/a of 2,6-xylenol ) and Honshu Chemical Industry Co. ( capacity 5000 of t/a 2,5-xylenol and chiefly 2,3,6-trimehyphenol by methylation of m-cresol ) all of which are in Japan Synthesis paths from methylbenzene There are three possible man-made paths from methylbenzene Sulfonation of methylbenzene Alkylation of methylbenzene with propene Chlorination of methylbenzene Sulfonation of methylbenzene: Sulfonation of methylbenzene is normally used in the production of p-cresol and o-cresol. Companies that makes usage of this procedure includes Inspec Fine Chemicals in United Kingdom ( 15000 -16000t/a ) Konan Chemicals, Japan ( 4000t/a ) Atul limited in India ( 5500t/a ) Commercial workss that employ the usage of Alkylation of methylbenzene with propene includes Mitsui Petrochemical Industries Limited and Sumitomo Chemical Co. Ltd which are both in Japan. The capacity of the workss are about 20,000t/a The lone commercial works in the universe that uses chlorination of methylbenzene is operated by BAYER AG in Germany. Easy handiness of Cl at a low monetary value might hold made Bayer s works still attractive. { 7 } Market Although used in aromas and nutrient additives, the chief markets for methyl phenol and xylenol are in the pharmaceutical and agrochemical industries. Pharmaceutical industry Cresol and xylenol derived functions, particularly p-cresol derived functions have been used as an of import intermediate in the pharmaceutical industry. Compounds derived from p-derivative include dilitiazem hydrochloride and trimethoprin. P-cresol derived functions such as Para-anisic aldehyde and p-anisic intoxicant have been used as feedstock for production of of import majority drugs. P-anisic aldehyde is used as a critical natural stuff in production of Dilitiazem. Dilitiazem hydrochloride is a calcium antagonist high blood pressure drug. It produces its antihypertensive consequence chiefly by relaxation of vascular smooth musculus and the attendant lessening in perepheral vascular opposition. The magnitude of blood force per unit area decrease is related to the grade of high blood pressure { 7 } . Introduced in the 1970s dilitiazem is presently being produced in Japan, India, Israel and Holland with the planetary production estimated at 1000t/a. it has been reported that there is expected growing of about 7-8 % in production of Dilitiazem during the following few old ages. It is besides of import to observe that India is presently the largest maker of p-anisic aldehyde. P-cresol have besides replaced Gallic acid as the get downing stuff for the production of 3,4,5-trimethoxy benzaldehyde which is later used in the synthesis of trimethoprim. States that make usage of the engineering for the for the synthesis of trimethoprin from 3,4,5-trimethoxy benzaldehyde includes USA, Canada, UK, Germany, France, Switzerland, Spain, Denmark and India. The planetary demand for trimethoprim is estimated to be around 500t/a with about 300t/a produced in India. These are merely two named illustrations of how methyl phenols and xylenols can be utilized in the pharmecutical industry. They serve as edifice blocks to legion other drugs which includes vitamin E. Going into the elaborate production of each drug produced is beyond the range of this study. However because of their huge application, the pharmaceutical industry is a moneymaking market for methyl phenol and xylenol and their derived functions. Agrochemicals The germicide, bactericidal and antifungal belongingss of Cresylic acids have been known for the last 60 old ages. Cresols were used in domestic application as bactericidal and para-chloro-meta-cresol is besides used as wood preservatives. However, it is non merely the first coevals derived functions of single methyl phenols but secondary and even third derived functions that have proved to be really of import works growing regulators or agrochemicals apart from their utilizations as family insect and pest repellants { 7 } As mentioned with the pharmaceutical industry, methyl phenol and xylenol are of import intermediate used in the production of agrochemicals, traveling into inside informations of the different agrochemical produced would be diversing from the chief intent of these study.

Sunday, November 24, 2019

John is the Man essays

John is the Man essays Marshall Mathers, better known as Eminem, has had many achievements in his life, but life wasn't always good. Growing up in a poor trailer park in Warren Mich. He failed out of ninth grade, which led to him dropping out of high school. He tried to go back but couldn't do it, he just wanted to rap and to be a star one day. Over the years he freestyle in some local clubs and participated in some competitions. It wasn't until 1997 that he was recognized, he won the Wake Up Show Freestyle Performer of the Year from L.A. Djs Sway and Tech and earned second place in Rap Sheet magazine's Rap Olympics, an annual freestyle rap competition. Then in 1998 he released The Slim Shady LP, his first known record. Slim Shady is the evil side of me, the sarcastic foul-mouthed side of me, Eminem says during and interview with the Source. In 2000 he released his second cd, The Marshall Mathers LP. Eminem has been known as one of the most provocative, controversial rappers in contemporary pop music. A l ot of people think he can get away with this because he is the first legitimate white rapper. I'm white in a music started by black people. I'm not ignorant to the culture and I'm not trying to take anything away from the culture, he said in his defense. But no one has a choice where they grew up or what color they are. If you're a kid or a ghetto kid you have no control over your circumstance. The only control you have is to get out of your situation or stay in it. There have been several attempts to keep Eminem from playing certain shows in his tour, because they think that his lyrics violate harassment categorically on the basis of sexual orientation and sex within the state or school. Don't take everything I say literally, Eminem said shortly after the album's debut, when furor over his lyrics mounted. I might say some things that are kinda left field, but that doesn't mean that every single thing I say, I mean. I may tend to push a lot of buttons and ...

Thursday, November 21, 2019

Crime in the Perception of Right-wing Essay Example | Topics and Well Written Essays - 2000 words

Crime in the Perception of Right-wing - Essay Example Right-wing criminologists fears the uncertainty of criminal behavior on the ground of racism, ethnicity and inequality and labels crime on the basis of social settings. While it is certainly true that right-wing political efforts are not always vague to obey traditional values, it does not follow that right-wing promotes fundamental school of thoughts in ceasing crime. In the course of this paper, we will discuss critically on what grounds crime spreads malaise and to what extent right wing draws a distinct line between causes and efforts to control crime and right-wing criminologist and the moralist. This will be further analysed in the light of critical criminological theory, which elaborate and assesses various efforts done in order to prevent crime. The rest of the analysis will critically analyse right-wing perspectives on violence, thereby locating the roots of criminality in the individual. This analysis will center around the realist aspect of the right-wing criminologists, t hat categorise crime under the heading of 'right realism' and relates more to a realistic view about the causes of crime and deviance than to a particular set of methodological principles. Right-wing criminologists, being strictly conservative perceive criminality in the context of those attempts that control and prevent criminal behavior. Therefore they possess the opinion that suggests solutions to the crime problem as couched in terms of a clear distinction between criminals and non-criminals, such that the behavior of the former has to be visualised as punishable. The contemporary economic and political scenario of any society reveals the extent to which most people are law-abiding and some criminals experience fear and predict an anticipated economic collapse among individuals, during times of economic uncertainty. Since right-wing never consider the economic consequences as the causes to spread crime, they perceive crime as policy-oriented institution which works in the absence of common culture and ethics. While blaming that criminals are due to our permissive social policies that allow unnecessary freedom to our society, they blame immigrants solely responsible for spreading malaise. The claim that right-wing conservatives believe that individuals are solely responsible for their acts and must be punished accordingly, arise two notions. First, that individuals are the cause of events that effect them, and secondly, the fact that individuals are responsible for making the most of the situation, in which they find themselves suitable to commit any crime. This explanation fits into the 'non-native' immigrants' who, robs the social sector from white-collar jobs and social security. Right-wing explanations about crime includes social policies which provides the right-wing thinkers an edge to contemplate upon the notion that by invariably attaching considerable weight to changes in social conditions as methods of 'reducing' crime, we are able to cease crime. Now, 'reducing' crime refers to 'reducing' the number of foreign immigrants to a country, i.e., to strict the